Electronic structure and self-assembling processes in platinum metalloporphyrins: photoemission and AFM studies
Autor: | Denis V. Vyalikh, A. I. Belogorokhov, S. A. Trophimov, V. D. Rumiantseva, Andrey M. Ionov, S. I. Bozhko, A. N. Chaika |
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Rok vydání: | 2008 |
Předmět: | |
Zdroj: | Applied Physics A. 94:473-476 |
ISSN: | 1432-0630 0947-8396 |
DOI: | 10.1007/s00339-008-4909-0 |
Popis: | The main goal of this paper is to investigate the electronic structure of valence band and core levels as well as surface topography of pristine tetraphenylporphyrin and Pt-based compounds Pt-TPP(p-COOH3)4, Pt-TPP(m-OCH3)4, PtCl2-TPP(m-OCH3)4 thin films. The electronic structure of various Pt-based metalloporphyrins which were investigated in dependence on their chemical structure and spectra were measured by high-resolution X-ray photoelectron spectroscopy (XPS) of valence band and Pt4f, Pt4d, C1s, O1s, N1s core levels. Results of atomic force microscopy (AFM) studies of topography and self-assembling processes in thin films of porphyrines are presented and discussed. |
Databáze: | OpenAIRE |
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