The role of protic solvent in asymmetric hydrogenation of methyl levulinate in the presence of a ruthenium-containing catalyst

Autor:	Maxim G. Vinogradov, O. V. Turova, V. A. Ferapontov, L. S. Gorshkova, E. V. Starodubtseva
Rok vydání:	2007
Předmět:	chemistry.chemical_compound Chemistry Asymmetric hydrogenation Noyori asymmetric hydrogenation Organic chemistry chemistry.chemical_element General Chemistry Methyl levulinate Catalysis Protic solvent Ruthenium BINAP
Zdroj:	Russian Chemical Bulletin. 56:552-554
ISSN:	1573-9171 1066-5285
DOI:	10.1007/s11172-007-0090-4
Popis:	A comparative study of asymmetric hydrogenation and deuteration of methyl levulinate catalyzed by the RuII—(S)-BINAP—HCl system (BINAP is 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl) in MeOH and MeOD was carried out. The results obtained suggest an important role of the protic solvent in the formation of catalytically active ruthenium complexes.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc2e19a7c8e7b7b0707478532faab96c https://doi.org/10.1007/s11172-007-0090-4 Zobrazit plný text záznamu Full text from SpringerLink