The photochemistry of α-nitrostilbenes and related compounds. A study of double bond cleavage following intramolecular cyclization and nitro-nitrite rearrangement

Autor:	RD Grant, JT Pinhey, E Rizzardo
Rok vydání:	1984
Předmět:	chemistry.chemical_classification Alpha cleavage Double bond Intramolecular reaction Chemistry Biocatalysis Stereochemistry Nitro General Chemistry Photochemistry Isomerization Aldehyde Bond cleavage
Zdroj:	Australian Journal of Chemistry. 37:1217
ISSN:	0004-9425
DOI:	10.1071/ch9841217
Popis:	A detailed study of the photochemistry of a number of α-nitrostilbenes is reported. The previously described intramolecular cyclization of (1) which resulted in cleavage of the double bond was not found to occur to any extent in the other compounds examined. The majority of the compounds were found to yield significant amounts of aldehydes and nitriles, which result from a new fragmentation pathway arising from initial photochemical nitro-nitrite isomerization.
Databáze:	OpenAIRE
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