Synthesis and Structure of Novel Metallacycle Complexes of Ruthenium Derived from 1,1′-Dialkynylferrocene

Autor:	Kiyotaka Onitsuka, Kenkichi Sonogashira, Toshikatsu Yoshida, Kayoko Miyaji, Tomohiro Adachi
Rok vydání:	1994
Předmět:	chemistry.chemical_compound chemistry Ferrocene Stereochemistry Polymer chemistry chemistry.chemical_element General Chemistry Metallacycle Ruthenium
Zdroj:	Chemistry Letters. 23:2279-2282
ISSN:	1348-0715 0366-7022
DOI:	10.1246/cl.1994.2279
Popis:	The reaction of 1,1′-bis(phenylethynyl)ferrocene with Ru3(CO)12 gave a novel trinuclear ruthenacycle complex having a [2]ferrocenophane skeleton. A similar treatment of 1,1′-bis(trimethylsilylethynyl)ferrocene afforded not only a trinuclear ruthenacycle analog but also a dinuclear ruthenacycle complex that also possessed a [2]ferrocenophane skeleton. These complexes were characterized by means of spectroscopic and X-ray diffraction analyses.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc160b39a0607246425468084ebc5d08 https://doi.org/10.1246/cl.1994.2279 Zobrazit plný text záznamu