Hydrogenation of citral to citronellol over Ni−Cr2O3

Autor:	A. M. Pak, S. R. Konuspaev, G. D. Zakumbaeva, D. V. Sokolskii
Rok vydání:	1981
Předmět:	Citronellol Chemistry Sodium chemistry.chemical_element Alcohol Citral Catalysis Solvent chemistry.chemical_compound Organic chemistry Physical and Theoretical Chemistry Solubility Sodium carbonate
Zdroj:	Reaction Kinetics and Catalysis Letters. 16:339-343
ISSN:	1588-2837 0133-1736
Popis:	Sodium carbonate added during citral hydrogenation to citronellol on Ni−Cr2O3 in C2−C5 alcohols increases the citronellol yield to 95%. According to microcalorimetric measurements, the conclusion is drawn that sodium adsorbs on the surface of metallic nickel, thus influencing the adsorbability with respect to various unsaturated groups and the selectivity. A correlation between hydrogen solubility in the alcohol solvent and the attainment of zero order with respect to hydrogen in citral hydrogenation to citronellol in the pressure range of 2–10 MPa is reported.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc0f698d7abfeb775497dc040daeba2c https://doi.org/10.1007/bf02066587 Zobrazit plný text záznamu Full text from SpringerLink