Raman studies of conjugation in polyfluoroaromatic compounds

Autor:	G.G. Furin, G.G. Yakobson, I.K. Korobeinicheva
Rok vydání:	1984
Předmět:	Electron pair Chemistry Stereochemistry Organic Chemistry chemistry.chemical_element Nitrogen Analytical Chemistry Inorganic Chemistry Crystallography symbols.namesake Fluorine symbols Raman spectroscopy Spectroscopy
Zdroj:	Journal of Molecular Structure. 114:395-398
ISSN:	0022-2860
DOI:	10.1016/0022-2860(84)87171-9
Popis:	Influence of the aromatic fluorine atoms in compounds of the type ArYAr ( Y = -NN-, -NN(O)-,-CN- ) and ArNSO on frequencies and intensities of stretching vibrations of functional groups in Raman spectra has been studied. The stretching frequencies of groups -NN-, -NN(O)-, -CHN-, -NSO are shown to be practically independent of position and number of fluorine atoms, but the intensities do depend. This is attributed to the changed effectivity of conjugation of nitrogen non-bonding electron pair with the aromatic π -system caused by the influence of fluorine atoms.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dc0b2a734bf0851ad4984c0386ccae46 https://doi.org/10.1016/0022-2860(84)87171-9 Zobrazit plný text záznamu