Polymer/Surfactant Interactions. Sodium Poly(styrene sulfonate) and CTAB Complex Formation. Light Scattering Measurements in Dilute Aqueous Solution

Autor:	Wyn Brown, Johan Fundin
Rok vydání:	1994
Předmět:	Aqueous solution Polymers and Plastics Chemistry Organic Chemistry Concentration effect Micelle Polyelectrolyte Styrene Inorganic Chemistry chemistry.chemical_compound Sulfonate Chemical engineering Pulmonary surfactant Ionic strength Polymer chemistry Materials Chemistry
Zdroj:	Macromolecules. 27:5024-5031
ISSN:	1520-5835 0024-9297
DOI:	10.1021/ma00096a026
Popis:	Light scattering measurements (dynamic and total intensity) have been made on the complex formed between the polyelectrolyte sodium poly(styrene sulfonate) (NaPSS) and the ionic surfactant cetyltrimethylammonium bromide (CTAB). The influence on the coil conformation of the weight concentration ratio CTAB/NaPSS, of the total concentration of the formed complex, of added simple salt, and of temperature have been examined. The NaPSS coil contracts strongly with increasing CTAB concentration. It is reasoned that this is due in part to the neutralization of the polyion charge by the oppositely charged surfactant micelles and in part through adaption of the coil conformation to the micellar surface curvature
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dbfcaf1809fd0dc6cb42dc25507ecca1 https://doi.org/10.1021/ma00096a026 Zobrazit plný text záznamu