Classification of growth behaviour for copper on various substrates with in-situ scanning probe microscopy
| Autor: | Heinrich Meyer, Richard J. Nichols, Helmut Baumgärtel, Elke Bunge |
|---|---|
| Rok vydání: | 1995 |
| Předmět: |
Chemistry
Nucleation chemistry.chemical_element Crystal growth Surfaces and Interfaces Substrate (electronics) Condensed Matter Physics Polypyrrole Copper Surfaces Coatings and Films law.invention Scanning probe microscopy chemistry.chemical_compound Crystallography law Monolayer Materials Chemistry Scanning tunneling microscope |
| Zdroj: | Surface Science. 335:110-119 |
| ISSN: | 0039-6028 |
| Popis: | In-situ scanning probe microscopy has been used to directly examine the deposition of copper on gold, polypyrrole and gold substrates which have been precovered with a multilayer copper film. The growth of the copper deposits, from electrolytes with and without additives, have been classified for these different substrates in accordance with Bauer [1] as either: (A) the Stranski-Krastanov mechanism involving the deposition of one or more layers followed by the formation of three-dimensional islands; (B) Frank-van der Merwe layer-by-layer growth of either individual monolayers (B1); or multilayer films (B2); or (C) the Volmer-Weber mechanism involving the formation of bulk islands directly on-top of the substrate. We show that the growth behaviour can be rationalised in terms of simple thermodynamic models which take into account, the strength of the deposit-substrate interaction and the crystallographic misfit between the deposit and the underlying substrate surface. |
| Databáze: | OpenAIRE |
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