Reversible Luminescent Vapochromism of a Zero-Dimensional Sb3+-Doped Organic–Inorganic Hybrid
| Autor: | Liang-Jin Xu, Cui-Mi Shi, Zhong-Ning Chen, Yue Wu, Ming Yang |
|---|---|
| Rok vydání: | 2021 |
| Předmět: |
Materials science
Photoluminescence Metal ions in aqueous solution Doping Quantum yield 02 engineering and technology engineering.material 010402 general chemistry 021001 nanoscience & nanotechnology Photochemistry 01 natural sciences 0104 chemical sciences Crystal Coating engineering General Materials Science Physical and Theoretical Chemistry 0210 nano-technology Luminescence Perovskite (structure) |
| Zdroj: | The Journal of Physical Chemistry Letters. 12:3288-3294 |
| ISSN: | 1948-7185 |
| DOI: | 10.1021/acs.jpclett.1c00418 |
| Popis: | Photoactive metal ions doping is an efficient way to modulate the photophysical properties of perovskite. Herein, we report a zero-dimensional (0D) InCl6(C4H10SN)4·Cl:Sb3+ by doping Sb3+ into InCl6(C4H10SN)4·Cl, which undergoes a significant enhancement of the emission peak at 550 nm with photoluminescence quantum yield boosting from 20% to 90%. Interestingly, a red-shifted emission is observed on InCl6(C4H10SN)4·Cl:Sb3+ upon exposure to ethanol and DMF vapor with the emission peak red-shifted from 550 to 580 and 600 nm, respectively. Furthermore, the transformation is reversed after drying the vapor-exposed InCl6(C4H10SN)4·Cl:Sb3+ at ambient conditions. Detailed characterizations reveal that the crystal packing and structure distortion account for the reversible luminescent vapochromism. Thanks to the superior stability and feasible transformation of InCl6(C4H10SN)4·Cl:Sb3+ at ambient conditions, a DMF sensor was fabricated by coating the mixture of InCl6(C4H10SN)4·Cl:Sb3+ and PMMA into patterned substrate, which exhibits an obvious luminescent change upon release and uptake of DMF and excellent stability and producibility in several cycles. |
| Databáze: | OpenAIRE |
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