Electronic structure and luminescence of tellurium (IV) halide complexes with guanidine and caesium cations

Autor: O.L. Shcheka, A. G. Mirochnik, A. A. Dotsenko, T. V. Sedakova, Vitaliy I. Vovna, Vladimir V. Korochentsev
Rok vydání: 2016
Předmět:
Zdroj: Journal of Molecular Structure. 1109:13-21
ISSN: 0022-2860
Popis: The present paper continues a series of publications on the investigation of complex compounds of s2 ions and their properties. The structure of the valence levels of Cs2TeX6, (HGu)2TeCl6 complexes (where Х = Cl, Br; HGu+ – guanidinium) is examined, the orbital nature of luminescence excitation is established, and the relationship of properties with the electronic structure is determined by means of X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT).
Databáze: OpenAIRE