Asymmetric hydrosilylation of olefins catalyzed by a chiral ferrocenylphosphine-palladium complex. Asymmetric synthesis of optically active alcohols and bromides from olefins

Autor:	Yoshio Katsuro, Kohei Tamao, Ichiro Nakae, Makoto Kumada, Tamio Hayashi
Rok vydání:	1980
Předmět:	inorganic chemicals Hydrosilylation Organic Chemistry Enantioselective synthesis chemistry.chemical_element Biochemistry Potassium fluoride Styrene Catalysis chemistry.chemical_compound chemistry Trichlorosilane Drug Discovery Organic chemistry Norbornene Palladium
Zdroj:	Tetrahedron Letters. 21:1871-1874
ISSN:	0040-4039
DOI:	10.1016/s0040-4039(00)92802-8
Popis:	Optically active norbornyl and 1-phenylethyl alcohols and bromides were obtained, respectively, from norbornyl- and 1-phenylethylpentafluorosilicates which were prepared by asymmetric hydrosilylation of norbornene and styrene with trichlorosilane catalyzed by a chiral ferrocenylphosphine-palladium complex followed by treatment with potassium fluoride.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::dbc162b95e192f4008e4124e5202812a https://doi.org/10.1016/s0040-4039(00)92802-8 Zobrazit plný text záznamu