Graphic model for calculating the entropy of С11Н24 alkanes with allowance for multiple non-valence interactions through three atoms along the chain of a molecule
| Autor: | D. Yu. Nilov, V. M. Smolyakov |
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| Rok vydání: | 2016 |
| Předmět: |
Alkane
chemistry.chemical_classification Thermodynamics 02 engineering and technology PARAFFIN HYDROCARBONS 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences 0104 chemical sciences Entropy (classical thermodynamics) chemistry Computational chemistry Molecule Physical and Theoretical Chemistry 0210 nano-technology |
| Zdroj: | Russian Journal of Physical Chemistry A. 90:1702-1705 |
| ISSN: | 1531-863X 0036-0244 |
| DOI: | 10.1134/s0036024416080203 |
| Popis: | A fourteen-constant graphic scheme is proposed for evaluating the thermodynamic properties of branched paraffin hydrocarbons. Absolute entropy Sf, 298 gas of 159 alkanes, of which 157 alkanes have yet to be studied experimentally, are calculated using 105 experimental data Sf, 298 K, gas for alkanes CН4–С32Н66. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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