Syntheses via anodically produced phenoxenium ions. Applications in the field of peptides and carbohydrates

Autor:	Klaus Regier, Anton Rieker, Rudolf Beisswenger
Rok vydání:	1991
Předmět:	Steric effects chemistry.chemical_classification Dipeptide Organic Chemistry Electrochemistry Biochemistry Combinatorial chemistry Ion chemistry.chemical_compound chemistry Nucleophile Aldose Drug Discovery Organic chemistry Phenols Acyl group
Zdroj:	Tetrahedron. 47:645-654
ISSN:	0040-4020
DOI:	10.1016/s0040-4020(01)87054-x
Popis:	Sterically hindered phenols are anodically oxidized to the corresponding phenoxenium ions which react with O- and N-nucleophiles to give cyclohexadienyl-protected nucleophiles. 4-Acyloxy substituted phenoxenium ions can transfer the acyl group to nucleophiles. A synthesis of dipeptides and glycoamino acids based on this principle is developed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db9b7f6f423474a5034c4f671352e799 https://doi.org/10.1016/s0040-4020(01)87054-x Zobrazit plný text záznamu