Synthesis and derivatization of highly-functionalized λ5-phospholes

Autor:	Marilín Vivanco, Santiago García-Granda, Javier Ruiz, Marta P. Gonzalo
Rok vydání:	2014
Předmět:	Phosphole Metals and Alloys General Chemistry Combinatorial chemistry Catalysis Cycloaddition Surfaces Coatings and Films Electronic Optical and Magnetic Materials chemistry.chemical_compound chemistry Materials Chemistry Ceramics and Composites Organic chemistry Derivatization
Zdroj:	Chem. Commun.. 50:5597-5599
ISSN:	1364-548X 1359-7345
Popis:	A variety of λ5-phosphole derivatives bearing up to three distinct peripheral functionalities have been prepared by regiospecific [3+2] cycloaddition reactions of the diphosphinoketenimine (PPh2)2CCNtBu (1) with electron-poor alkenes. Selective derivatization of the exocyclic functional groups, including formation of dimetallic complexes with a phosphole core, was subsequently accomplished.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db8dde6645a7111d4d9fc84ac69ee87f https://doi.org/10.1039/c4cc02089h Zobrazit plný text záznamu