Acid-catalyzed reaction of 3-methylbut-3-ene-1-ol with formaldehyde

Autor:	G. K. Oparina, M. K. Bychkova, V. P. Babukh, V. Z. Sharf, V. I. Heifets, L. Kh. Freidlin
Rok vydání:	1968
Předmět:	Reaction conditions chemistry.chemical_compound chemistry Acid catalyzed Yield (chemistry) Condensation Formaldehyde Organic chemistry Alcohol Triol General Chemistry Ene reaction
Zdroj:	Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 17:1064-1066
ISSN:	1573-9171 0568-5230
DOI:	10.1007/bf00910846
Popis:	1. We have studied the effect of the reaction conditions on the mode of condensation of 3-methylbut-3-ene-1-ol with formaldehyde. 2. The decisive factors directing the process towards preferential formation of dioxane alcohol or triol are the ratio of water to formladehyde and of methylbutenol to formaldehyde. 3. We have found the optimum conditions, at which the yield of dioxane alcohol reaches 96% of the theoretical, calculated in terms of methylbutenol.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db83a292ed3caf3dacccd8545a3e95c5 https://doi.org/10.1007/bf00910846 Zobrazit plný text záznamu Full text from SpringerLink