Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

Autor: Klaus Jacob, Ivan Pavlík, Claus Pietzsch, Martin Pavlišta, Tomáš Lébl, Jaromír Vinklárek
Rok vydání: 2000
Předmět:
Zdroj: Collection of Czechoslovak Chemical Communications. 65:23-34
ISSN: 1212-6950
0010-0765
DOI: 10.1135/cccc20000023
Popis: (Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)6 and W(CO)6 under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcR·M(CO)5 (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mössbauer spectroscopy.
Databáze: OpenAIRE