Synthesis and Characterization of Heterodinuclear Complexes Pentacarbonyl[(dimethylaminomethyl)ferrocene]molybdenum and Pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten
Autor: | Klaus Jacob, Ivan Pavlík, Claus Pietzsch, Martin Pavlišta, Tomáš Lébl, Jaromír Vinklárek |
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Rok vydání: | 2000 |
Předmět: | |
Zdroj: | Collection of Czechoslovak Chemical Communications. 65:23-34 |
ISSN: | 1212-6950 0010-0765 |
DOI: | 10.1135/cccc20000023 |
Popis: | (Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)6 and W(CO)6 under substitution of one CO group and formation of the donor-acceptor complexes of the formula HFcR·M(CO)5 (M = Mo, W). These yellow microcrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mössbauer spectroscopy. |
Databáze: | OpenAIRE |
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