The Synthesis and Reactions of 2,6-Dimethyl-4-silaspiro[3.4]oct-6-ene

Autor:	Hiroyuki Nohira, Noriyuki Shibuya, Daiyo Terunuma
Rok vydání:	1982
Předmět:	Dimethyl acetylenedicarboxylate chemistry.chemical_compound chemistry Magnesium chemistry.chemical_element Organic chemistry General Chemistry Isoprene Ene reaction Tetrahydrofuran
Zdroj:	Bulletin of the Chemical Society of Japan. 55:2287-2288
ISSN:	1348-0634 0009-2673
DOI:	10.1246/bcsj.55.2287
Popis:	A new silaspiro compound, i.e., 2,6-dimethyl-4-silaspiro[3.4]oct-6-ene, was synthesized by treating 1,1-dichloro-3-methyl-1-silacyclobutane with isoprene in the presence of magnesium in tetrahydrofuran. The reactions of the silaspiro compound with LiAlH4, H2PtCl6, dimethyl acetylenedicarboxylate in the presence of PdCl2(PPh3)2, and the Simmons-Smith agent were investigated.
Databáze:	OpenAIRE
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