Studies on cyclohexane derivatives. Part VI: cis- and trans-1,4-Di-t-butylcyclohexane. Preparation and properties

Autor:	H. Dekker, C. Mosselman, J. H. Palm, P. E. Verkade, L. Schäfer, M. A. Hoefnagel, L. de Lavieter, B. M. Wepster, A. Wemmers, G. Somsen, H. van Bekkum, A. van Veen
Rok vydání:	2010
Předmět:	chemistry.chemical_compound Liquid state Strain (chemistry) Cyclohexane chemistry Stereochemistry Enthalpy T-butylcyclohexane General Chemistry Medicinal chemistry Cis–trans isomerism
Zdroj:	Recueil des Travaux Chimiques des Pays-Bas. 86:1363-1371
ISSN:	0165-0513
Popis:	cis- and trans-1,4-Di-t-butylcyclohexane have been prepared. Evidence is presented showing that the cis-isomer is mainly in a non-chair conformation. The enthalpy difference between the two isomers in the liquid state at 25° is 4.7 kcal/mole, the trans-isomer having the lower strain.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db6e46ee2fc760022e0756479c91aaa9 https://doi.org/10.1002/recl.19670861213 Zobrazit plný text záznamu