Coordination chemistry and extraction properties of phosphonopyridyl N,P oxides
Autor: | X Gan, John R. FitzPatrick, Evelyn M. Bond, Robert T. Paine |
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Rok vydání: | 1998 |
Předmět: |
chemistry.chemical_classification
Valence (chemistry) Ligand Mechanical Engineering Inorganic chemistry Extraction (chemistry) Metals and Alloys Nitrone Coordination complex chemistry Mechanics of Materials Liquid–liquid extraction Polymer chemistry Materials Chemistry Molecule Group 2 organometallic chemistry |
Zdroj: | Journal of Alloys and Compounds. :172-175 |
ISSN: | 0925-8388 |
DOI: | 10.1016/s0925-8388(98)00048-6 |
Popis: | The coordination chemistry of 6,6-bis(diphenylphosphinomethyl)-2,2′-bipyridine-N,N′,P,P′-tetra oxide with Eu(NO3)3 is described. The ligand forms a 2:1 complex in which both ligands bind in a tetradentate fashion to the metal. The liquid–liquid extraction of Am(III) in HNO3 solutions by the ligand in CHCl3 is also outlined. |
Databáze: | OpenAIRE |
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