Coordination chemistry and extraction properties of phosphonopyridyl N,P oxides

Autor: X Gan, John R. FitzPatrick, Evelyn M. Bond, Robert T. Paine
Rok vydání: 1998
Předmět:
Zdroj: Journal of Alloys and Compounds. :172-175
ISSN: 0925-8388
DOI: 10.1016/s0925-8388(98)00048-6
Popis: The coordination chemistry of 6,6-bis(diphenylphosphinomethyl)-2,2′-bipyridine-N,N′,P,P′-tetra oxide with Eu(NO3)3 is described. The ligand forms a 2:1 complex in which both ligands bind in a tetradentate fashion to the metal. The liquid–liquid extraction of Am(III) in HNO3 solutions by the ligand in CHCl3 is also outlined.
Databáze: OpenAIRE