Syntheses, structures, 113Cd solution NMR chemical shifts, and investigations of fluxional processes of bis[poly(pyrazolyl)borato]cadmium complexes

Autor:	Robert L. Ostrander, Scott S. Mason, Daniel L. Reger, Arnold L. Rheingold
Rok vydání:	1993
Předmět:	Inorganic Chemistry Crystallography Cadmium Chemistry Stereochemistry Chemical shift X-ray crystallography Molecule chemistry.chemical_element Crystal structure Nuclear magnetic resonance spectroscopy Physical and Theoretical Chemistry
Zdroj:	Inorganic Chemistry. 32:5216-5222
ISSN:	1520-510X 0020-1669
Popis:	The reactions of 2 equiv of K[H 2 B(pz) 2 ], K[HB(pz) 3 ], K[B(pz) 4 ], K[H 2 B(3,5-Me 2 pz) 2 ], K[HB(3,5-Mc 2 pz) 3 ], and K[B(3-Mepz) 4 ] with CdCl 2 lead to the formation of Se respective [poly(pyrazolyl)borato] 2 Cd complexes in high yields. A similar reaction with a 1/1 mixture of K[HB(3,5-Me 2 pz) 3 ] and either K[H 2 B(pz) 2 ] or K[B(pz) 4 ] yields [HB(3,5-Me 2 pz) 3 ]Cd[H 2 B(pz) 2 ] (7) or [HB(3,5-Me 2 pz) 3 ]Cd[B(pz) 4 ] (8), respectively
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db61a6fbd611de09bea64a82b5199ed0 https://doi.org/10.1021/ic00075a046 Zobrazit plný text záznamu