Metallkomplexe mit biologisch wichtigen liganden

Autor: Joachim Meder, Wolfgang Beck, Wolfgang Petri
Rok vydání: 1980
Předmět:
Zdroj: Journal of Organometallic Chemistry. 191:73-77
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)88556-3
Popis: Anionic tricarbonyl- l -histidinato complexes of molybdenum and tungsten [M(CO)3( l -histidinato)]− (M = Mo, W), have been prepared by reaction of the anion of l -histidine with Mo(CO)6 or W(CO)3(CH3CN)3. The complexes react with isoamyl nitrite and allyl chloride to give M(CO)2(NO)( l -histidinate) and M(CO)2(allyl)( l -histidinate), respectively.
Databáze: OpenAIRE