Nitrocellulose Membrane, Modified by RC(S)NHP(X)(OiPr)2(X = S, R = PhNH; X = O, R = PhNH, Ph), for Sorption Extraction of Cobalt Cations

Autor:	Maria G. Babashkina, Felix D. Sokolov, Axel Klein, Damir A. Safin
Rok vydání:	2010
Předmět:	chemistry.chemical_classification Aqueous solution Organic Chemistry Inorganic chemistry Extraction (chemistry) chemistry.chemical_element Sorption Biochemistry Inorganic Chemistry chemistry.chemical_compound Membrane chemistry Thiourea Cobalt Nitrocellulose Thioamide Nuclear chemistry
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 185:1815-1822
ISSN:	1563-5325 1042-6507
Popis:	The complexation and extraction properties of RC(S)NHP(X)(OiPr)2 [X = S, R = PhNH (HLI); X = O, R = PhNH (HLII), Ph (HLIII)] towards cobalt cations were studied. The nitrocellulose membrane was used as a carrier for HLI−III. The maximal degree of extraction of cobalt cations from an aqueous solution is observed at pH = 7.8–8.4. It was established that complexes formed are kept in a water solution on a surface of the carrier and washed away in 96% aqueous ethanol. The membrane modified by HLI allows extraction and concentration of Co(II) selectively, while the modification by HLIII leads to the selective extraction of Co(III).
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db52cce8f5228b46e8a505a510e694c7 https://doi.org/10.1080/10426500903329211 Zobrazit plný text záznamu