Kinetic and Thermodynamic Parameters of the Thermal Decomposition of Some Metal Complexes of 4-Benzamido-3-Thiosemicarbazone Derivatives

Autor:	M. E. M. Emam
Rok vydání:	2002
Předmět:	Thermogravimetric analysis chemistry.chemical_compound Order of reaction Chemistry Differential thermal analysis Thermal decomposition Enthalpy Pyridine Physical chemistry Thermal stability General Chemistry Activation energy
Zdroj:	Journal of the Chinese Chemical Society. 49:319-323
ISSN:	0009-4536
Popis:	The kinetic and thermodynamic parameters such as reaction order, activation energy, enthalpy, free energy and entropy change related to the thermal decomposition of Co(II), Ni(II) and Cu(II) hydrazone complexes of 4-benzamido-1-(4-actylpyridine)-3-thiosemicarbazone (BACPT) and 4-benzamido-1-(pyridine -3-aldehye)-3-thiosemicarb-azone (BAPT) were evaluated from differential thermal analysis (DTA) curves using Thomas-Clarke's method. The thermal stability of these complexes are discussed in relation to the nature ofthe metal ion and ofthe ligand present. A suitable mechanism for the thermal decomposition process of the complexes based on the data of the thermogravimetric analysis (TGA) was suggested.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db4037f8c619229685deee73ae1e9ea4 https://doi.org/10.1002/jccs.200200049 Zobrazit plný text záznamu Plný text