Proton conducting system (ImH 2 ) 2 SeO 4 ·2H 2 O investigated with vibrational spectroscopy
| Autor: | Sylwia Zięba, Andrzej Łapiński, Adam Mizera, Katarzyna Pogorzelec-Glaser |
|---|---|
| Rok vydání: | 2017 |
| Předmět: |
Hydrogen bond
Inorganic chemistry Infrared spectroscopy Protonation 02 engineering and technology 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Selenate Atomic and Molecular Physics and Optics 0104 chemical sciences Analytical Chemistry Crystal chemistry.chemical_compound symbols.namesake chemistry symbols Physical chemistry Imidazole Molecule 0210 nano-technology Raman spectroscopy Instrumentation Spectroscopy |
| Zdroj: | Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 180:224-233 |
| ISSN: | 1386-1425 |
| Popis: | Imidazolium selenate dihydrate (ImH 2 ) 2 SeO 4 ·2H 2 O crystals have been investigated using Raman and IR spectroscopy. Experimental data were supported by the quantum-chemical calculations (DFT), Hirshfield surfaces and fingerprint plots analysis, and Bader theory calculations. The imidazolium selenate dihydrate crystal exhibits high proton conductivity of the order of ~ 10 − 1 S/m at T = 333 K. The spectra of this compound are dominated by bands related to the lattice modes, the internal vibrations of the protonated imidazole cation, selenate anion, water molecules, and hydrogen bonds network. For the imidazolium selenate dihydrate crystal, the formal classification of the fundamental modes has been carried out. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
|
Full Text from ScienceDirect