ChemInform Abstract: High Pressure Assisted 1,3-Dipolar Cycloadditions: Formation of 1,2,3-Triazoles from Aryl Azides and (Trimethylsilyl)acetylene

Autor:	Paolo Zanirato, Aldo Brillante, Valeria Melai
Rok vydání:	2010
Předmět:	Reaction rate chemistry.chemical_compound Dipole chemistry Trimethylsilyl Acetylene Aryl Yield (chemistry) General Medicine Fourier transform infrared spectroscopy Photochemistry Cycloaddition
Zdroj:	ChemInform. 30
ISSN:	1522-2667 0931-7597
Popis:	The cycloaddition of aryl azides to the corresponding 1,2,3-triazoles has been studied by means of FTIR spectroscopy in a diamond anvil cell at pressures up to 1 GPa. The rate of reaction increases logarithmically with pressure and the yield is close to quantitative.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::db248bfdb74c3531e98dc9ed71c0e407 https://doi.org/10.1002/chin.199910042 Zobrazit plný text záznamu Plný text