Functionally substituted organotin compounds
| Autor: | S.Z. Abbas, R.C. Poller |
|---|---|
| Rok vydání: | 1976 |
| Předmět: |
Diphenyltin chloride
Organic Chemistry Phosphorus pentachloride Oxime Biochemistry Medicinal chemistry Inorganic Chemistry chemistry.chemical_compound Tosyl chemistry Amide Mössbauer spectroscopy Beckmann rearrangement Materials Chemistry Organic chemistry Physical and Theoretical Chemistry Derivative (chemistry) |
| Zdroj: | Journal of Organometallic Chemistry. 104:187-191 |
| ISSN: | 0022-328X |
| DOI: | 10.1016/s0022-328x(00)91668-1 |
| Popis: | The structures of the oximes formed from (4-oxopentyl)triphenyltin and (4-oxopentyl)diphenyltin chloride have been determined using IR, PMR and Mossbauer spectroscopy. Beckmann rearrangement of (4-oximinopentyl)diphenyltin chloride with phosphorus pentachloride gave the amide resulting from exchange of syn groups. Treatment of the second oxime with phosphorus pentachloride caused other reactions but the O -tosyl derivative was rearranged under mild conditions to give a mixture of amides. |
| Databáze: | OpenAIRE |
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