Applicability of emf measurements under external load resistance conditions for ion transport number determination

Autor: Aleksey A. Yaremchenko, Vladislav V. Kharton, Jorge R. Frade, Ekaterina V. Tsipis
Rok vydání: 2005
Předmět:
Zdroj: Journal of Solid State Electrochemistry. 10:96-103
ISSN: 1433-0768
1432-8488
DOI: 10.1007/s10008-005-0667-5
Popis: In order to evaluate the applicability of concentration cells for the ion transference number measurements with external load, the cell response was simulated with variable transport properties of the cell material, external load resistance, geometrical factors such as ion-conducting membrane thickness, and electrode kinetics. This technique is expected to be pertinent when ηF/RT
Databáze: OpenAIRE