Synthesis and photoelectrochemical characterization of a high molar extinction coefficient heteroleptic ruthenium(II) complex
Autor: | Varun Kumar Singh, M Srinivasu, V. Gopal Reddy, Ch. Vijay Kumar, P. Yella Reddy, Lingamallu Giribabu, Y Soujnya |
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Rok vydání: | 2011 |
Předmět: | |
Zdroj: | Journal of Chemical Sciences. 123:371-378 |
ISSN: | 0973-7103 0974-3626 |
Popis: | A new high molar extinction coefficient heteroleptic ruthenium(II) complex (m-BL-1) that contains a 4,4’4”-tricaboxy-2,2’:6’,2”-terpyridine, 4,4’-bis-[3,5-di-tert-butyl-phenyl)-vinyl]-[2,2’]bipyridyl and a thiocyanate ligand in its molecular structure has been synthesized and completely characterized by CHN, Mass, 1H-NMR, UV-Vis, and fluorescence spectroscopies as well as cyclic voltammetry. The new sensitizer was tested in dye-sensitized solar cells using three different redox electrolytes and compared its performance to that of standard sensitizer black dye. |
Databáze: | OpenAIRE |
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