Synthesis and photoelectrochemical characterization of a high molar extinction coefficient heteroleptic ruthenium(II) complex

Autor:	Varun Kumar Singh, M Srinivasu, V. Gopal Reddy, Ch. Vijay Kumar, P. Yella Reddy, Lingamallu Giribabu, Y Soujnya
Rok vydání:	2011
Předmět:	Thiocyanate Ligand Inorganic chemistry chemistry.chemical_element General Chemistry Molar absorptivity Ruthenium chemistry.chemical_compound Dye-sensitized solar cell chemistry Molecule Terpyridine Cyclic voltammetry Nuclear chemistry
Zdroj:	Journal of Chemical Sciences. 123:371-378
ISSN:	0973-7103 0974-3626
Popis:	A new high molar extinction coefficient heteroleptic ruthenium(II) complex (m-BL-1) that contains a 4,4’4”-tricaboxy-2,2’:6’,2”-terpyridine, 4,4’-bis-[3,5-di-tert-butyl-phenyl)-vinyl]-[2,2’]bipyridyl and a thiocyanate ligand in its molecular structure has been synthesized and completely characterized by CHN, Mass, 1H-NMR, UV-Vis, and fluorescence spectroscopies as well as cyclic voltammetry. The new sensitizer was tested in dye-sensitized solar cells using three different redox electrolytes and compared its performance to that of standard sensitizer black dye.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::da6b1ebaede01e4bc752df0f256f14da https://doi.org/10.1007/s12039-011-0096-1 Zobrazit plný text záznamu Plný text ve formátu PDF