Correlation between entropy and enthalpy factors during heterogeneous complex catalytic reactions

Autor:	S. Veleva, E. Valtcheva
Rok vydání:	1988
Předmět:	Compensation effect Correlation symbols.namesake Departure function Adsorption Chemistry Enthalpy symbols Thermodynamics Physical and Theoretical Chemistry Catalysis Gibbs free energy
Zdroj:	Reaction Kinetics and Catalysis Letters. 37:127-132
ISSN:	1588-2837 0133-1736
Popis:	The correlation equations are discussed between entropy and enthalpy factors during complex heterogeneous catalytic reactions based on the dependence of the Gibbs energy on the surface coverage. The existence of the entropy heterogeneity in the adsorption layer leads to the correlations between ΔSθ and ΔHθ. In the cases where the increase of ΔHθ is accompanied by an increase of ΔSθ, i. e. when the entropy factors lead to a decrease of the interval of heterogeneity, the known thermodynamic compensation effect is observed.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::da56f7056cfd677f22bd5cd14e2fc92c https://doi.org/10.1007/bf02061721 Zobrazit plný text záznamu Full text from SpringerLink