Synthesis and crystal structure of the first metallaborane cluster containing three rings of exo-polyhedral cyclization

Autor:	Jian-Min Dou, Jie Sun, Jing-De Wei, Pei-Ju Zheng, Chunhua Hu
Rok vydání:	1997
Předmět:	Inorganic Chemistry Diffraction Crystallography Chemistry Stereochemistry Materials Chemistry Cluster (physics) Crystal structure Physical and Theoretical Chemistry
Zdroj:	Polyhedron. 16:3873-3875
ISSN:	0277-5387
DOI:	10.1016/s0277-5387(97)00118-6
Popis:	The novel nido 11-vertex nickelaborane [{μ-3,7(PhCOS)}-{μ-7,8-(PhCOS)}-{μ-7,11-(PhCOS)}-10-PPh 3 nido -7-NiB 10 H 7 ] ( 1 ) was synthesized and characterized by X-ray diffraction analysis. This the first metallaborane cluster that has three rings of exo -polyhedral cyclization.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::da4e48871bdbfbd9de312bbacb4395bf https://doi.org/10.1016/s0277-5387(97)00118-6 Zobrazit plný text záznamu Full Text from ScienceDirect