Energetic Materials Trends in 5‐ and 6‐Membered Cyclic Peroxides Containing Hydroperoxy and Hydroxy Substituents

Autor:	Philip D. Martin, Benedikt Stiasny, G. Andrés Cisneros, Nipuni Dhanesha H Gamage, Charles H. Winter, Jörg Stierstorfer, Eric G. Kratz, Thomas M. Klapötke
Rok vydání:	2016
Předmět:	Primary (chemistry) 010405 organic chemistry Hydrogen bond Solid-state Materials testing Nuclear magnetic resonance spectroscopy 010402 general chemistry 01 natural sciences Peroxide 0104 chemical sciences Highly sensitive Inorganic Chemistry chemistry.chemical_compound chemistry Organic chemistry
Zdroj:	European Journal of Inorganic Chemistry. 2016:5036-5043
ISSN:	1099-0682 1434-1948
Popis:	Ten peroxide compounds based upon the 3,6-di(hydroperoxy)-1,2-dioxane, 2-hydroxy-6-hydroperoxy-1,2-dioxane, 3,5-di(hydroperoxy)-1,2-dioxolane, and 3-hydroxy-5-hydroperoxy-1,2-dioxolane skeletons have been synthesized, structurally characterized, and fully evaluated for their energetic materials properties. The solid state structures of these compounds are dominated by hydrogen bonding interactions involving the hydroperoxy and hydroxy groups. Energetic materials testing shows that most of the compounds are highly sensitive toward impact and friction, with similar properties to highly sensitive peroxides such as triacetone triperoxide. 3,5-Diethyl-5-hydroperoxy-1,2-dioxolan-3-ol (3b) and 3,5-dimethyl-5-hydroperoxy-1,2-dioxolan-3-ol (5b) have lower impact and friction sensitivities than the other compounds, with values that are appropriate for use as primary explosives.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::da3647072f87048ca6cdbf27937f9416 https://doi.org/10.1002/ejic.201600767 Zobrazit plný text záznamu Plný text ve formátu PDF Plný text ve formátu HTML
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