Annulation Reactions of Chiral Vinylsulfonium Salts with 2-Indolecarboxaldehyde

Autor:	Kyung-hee Kim, Leslie S. Jimenez, Sammy Metobo
Rok vydání:	2001
Předmět:	Inorganic Chemistry chemistry.chemical_compound Annulation chemistry Organic Chemistry Bicyclic Heterocyclic Compounds Sodium azide Organic chemistry Alcohol Biochemistry Asymmetric induction Indolecarboxaldehyde
Zdroj:	Phosphorus, Sulfur, and Silicon and the Related Elements. 176:29-47
ISSN:	1563-5325 1042-6507
DOI:	10.1080/10426500108055100
Popis:	The preparation of the chiral uinylsulfonium salts 4, 5, and 6 is described. Their use in an annulation with 2-indolecarboxaldehyde and sodium azide proceeds to form the azido alcohol 2 with low asymmetic induction. These results represent an initial investigation of the asymmetric induction obtained from enantiomerically pure vinylsulfonium salts.
Databáze:	OpenAIRE
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