The Chemical Mechanism of the Formation of Fluorite-Barite-Siderite Carbonatite in Karasug Fe-F-Ba-Sr-REE Deposit

Autor: Alexander V. Bolonin
Rok vydání: 2018
Předmět:
Zdroj: Open Journal of Geology. :399-403
ISSN: 2161-7589
2161-7570
DOI: 10.4236/ojg.2018.84023
Popis: Intrusive fluorite-barite-siderite carbonatite of Karasug deposit (Tuva) crystallized from ionic salt melt is dominated by iron chloride with the participation of alkali metal salts. Melt composition and main reaction of mineral formation: NaFeCl3 + 4KF + 2Na2Ca(CO3)2 + Na2Ba(CO3)2 + Na2SO4 = 6FeCO3 + 2CaF2 + BaSO4 + 14NaCl + 4KCl. The highest temperature (550°C - 650°C) brine-melt inclusions in minerals are pseudo-primary. Their predominant Na-K-chloride composition does not correspond to the primary melt, but is close to the residual brine-melt.
Databáze: OpenAIRE