A Li–O2/Air Battery Using an Inorganic Solid-State Air Cathode

Autor:	Yungui Chen, Xiaofei Wang, Shengrong Cai, Ding Zhu, Lei Zhang, Ming Song
Rok vydání:	2014
Předmět:	Battery (electricity) Materials science Volatilisation Inorganic chemistry chemistry.chemical_element Electrolyte Electrochemistry Cathode law.invention Anode chemistry law General Materials Science Lithium Porosity
Zdroj:	ACS Applied Materials & Interfaces. 6:11204-11210
ISSN:	1944-8252 1944-8244
DOI:	10.1021/am501315n
Popis:	The “(−) lithium (Li) anode|organic anolyte + inorganic catholyte|solid-state cathode (+)” Li–O2/air battery based on an inorganic solid-state air cathode was fabricated with a simple method. The electrochemical performance and reaction products of the Li–O2/air batteries under pure O2 and ambient air were investigated, respectively. The inorganic Li-ion conductive solid-state electrolyte Li1.3Al0.3Ti1.7(PO4)3 was stable during cycling and avoided the decomposition and volatilization problems that conventional organic electrolytes faced. Moreover, the porous air cathode provided a sufficient gas-phase O2-transport channel, facilitating the achievement of a high capacity of 14192 or 7869 mA h g–1 under pure O2 or ambient air, respectively. Our results demonstrate that the Li–O2/air battery using an inorganic porous air cathode has a great potential for practical application.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::da20a94eab31731f4288edb95aba4fe6 https://doi.org/10.1021/am501315n Zobrazit plný text záznamu