Chemical Synthesis of (4,6-Pyr)-Gal β1→4GlcNAcβ1→3Fucβ1→OMe: A Pyruvated Trisaccharide Related to the Cell Aggregation of the SpongeMicrociona Prolifera
Autor: | Shaojiang Deng, Yongzheng Hui, Zhong‐Wu Guo, Biao Yu |
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Rok vydání: | 1998 |
Předmět: | |
Zdroj: | Journal of Carbohydrate Chemistry. 17:439-452 |
ISSN: | 1532-2327 0732-8303 |
DOI: | 10.1080/07328309808002904 |
Popis: | 4,6-O-[(R)-1-carboxylethylidene]Galβ1 →4GlcNAcβ1 →3Fucβ1 →OMe, a pyruvated trisaccharide unit involved in the aggregation factor of the marine sponge Microciona prolifera, was synthesized stereospecifically and unambiguously employing thioglycosides as glycosyl donors to construct glycosidic bonds. |
Databáze: | OpenAIRE |
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