Preparation of higher adamantane homologues by reaction of adamantan-1-ol with heptenes in sulfuric acid
Autor: | Luděk Vodička, Josef Janků, J. Burkhard |
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Rok vydání: | 1980 |
Předmět: | |
Zdroj: | Collection of Czechoslovak Chemical Communications. 45:835-842 |
ISSN: | 1212-6950 0010-0765 |
Popis: | Reaction of adamantan-1-ol with heptenes in conc. sulfuric acid affords a complicated mixture of hydrocarbons, containing heptyladamantanes, diheptyladamantanes, tetradecyladamantanes, diadamantylheptanes and adamantyl-heptyladamantylheptanes. The reaction mixture can be separated into narrower fractions containing hydrocarbons of approximately equal molecular weight. The method can be utilized for the preparation of technical mixtures of high-boiling alkyladamantanes. |
Databáze: | OpenAIRE |
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