Multiphoton multi laser spectroscopy of the ν3 mode of SF6 in a molecular beam

Autor: A.F. Linskens, J. Reuss, G. Pierre, B. Sartakov, S. te Lintel Hekkert, Iwan Holleman
Rok vydání: 1993
Předmět:
Zdroj: Chemical Physics. 176:171-184
ISSN: 0301-0104
Popis: Results are presented of measurements utilizing two counter propagating CO 2 waveguide lasers interacting simultaneously with SF 6 molecules in a molecular beam. 95 new two-photon transitions were observed and assigned, for combinations of two different CO 2 laser lines. Especially transitions to levels of E g vibrational symmetry provide new information on the parameters of the Hamiltonian because previous one-colour measurements could barely access these levels. Still no transitions were found to levels with A 1g vibrational symmetry. Some results are presented on three- and four-photon transitions.
Databáze: OpenAIRE