Direct Synthesis of Allyl Sulfides from Allyl Alcohols and Thiols

Autor:	Lung Ching Lin, Daniel B. King, Chi C. Shum, Jih Ru Hwu, Sheng Fa Yu, Shwu-Chen Tsay, Buh-Luen Chen, Paul A. Furth
Rok vydání:	1993
Předmět:	chemistry.chemical_compound chemistry Cinnamyl alcohol Bicyclic molecule Thiophenol Organic Chemistry Organic chemistry Ether Alcohol Chemoselectivity Allyl Sulfide Catalysis Dichloromethane
Zdroj:	Synthesis. 1993:329-334
ISSN:	1437-210X 0039-7881
Popis:	In the presence of boron trifluoride-diethyl ether complex, various allyl alcohols [(-)-myrtenol, geraniol, cinnamyl alcohol, linalool, 1-octen-3-ol, 2-hydroxybenzyl alcohol and bicyclic diols] were reacted with thiophenol, 1-butanethiol, trimethyl(phenylthio)silane or hexamethylsilane in dichloromethane at room temperature to give the corresponding allyl sulfides in good to excellent yields. The mild conditions for this transformation allowed chemoselectivity
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9fa6971759cf7a021531506f64cb7d3 https://doi.org/10.1055/s-1993-25860 Zobrazit plný text záznamu