Methyltrioxorhenium: oxidative cleavage of CC-double bonds and its application in a highly efficient synthesis of vanillin from biological waste

Autor:	Thomas Weskamp, Richard W. Fischer, Jochen P Zoller, Wolfgang A. Herrmann
Rok vydání:	2000
Předmět:	chemistry.chemical_classification Double bond Process Chemistry and Technology Carboxylic acid Vanillin Aldehyde Catalysis Ferulic acid chemistry.chemical_compound Isoeugenol chemistry Organic chemistry Phenols Physical and Theoretical Chemistry
Zdroj:	Journal of Molecular Catalysis A: Chemical. 153:49-52
ISSN:	1381-1169
DOI:	10.1016/s1381-1169(99)00370-2
Popis:	An oxidation system consisting of methyltrioxorhenium and H 2 O 2 catalyzes the cleavage of CC-double bonds. By varying the reaction conditions, it is possible to generate either the aldehyde or the carboxylic acid in reasonable-to-excellent yields and selectivities, depending on the starting material. The application of these findings to isoeugenol and trans -ferulic acid — both available from renewable resources — results in a highly efficient synthesis of vanillin.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9de3d7b643ae2296d6f392b4450cdf5 https://doi.org/10.1016/s1381-1169(99)00370-2 Zobrazit plný text záznamu Full Text from ScienceDirect