Mechanism for gas formation in polyethylene catalytic decomposition

Autor:	Yumiko Ishihara, Tomoyuki Takesue, Katsuhiko Saido, Hidesaburo Nanbu, Tadashi Ikemura
Rok vydání:	1992
Předmět:	Reaction mechanism Polymers and Plastics Chemistry Organic Chemistry Polyethylene Butene Catalysis Ion chemistry.chemical_compound Carbonium ion Chemical engineering Materials Chemistry Isobutane Organic chemistry Chemical decomposition
Zdroj:	Polymer. 33:3482-3486
ISSN:	0032-3861
DOI:	10.1016/0032-3861(92)91107-d
Popis:	Gas formation mechanisms were studied in detail to find means for the selective recovery of specific components through catalytic gasification of polyethylene. Isobutene and butanes were obtained, respectively, by β-scission from chain-end tertiary carbonium ions and by the hydrogenation of butene. The selective recovery of isobutane was possible by controlling reaction conditions such as temperature, reactor shape and, particularly, the exit temperature for gaseous products.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9be8a3bc6c60f33d411352dde0891d7 https://doi.org/10.1016/0032-3861(92)91107-d Zobrazit plný text záznamu