Cobalt(II) and zinc complexes of 2-acetyl- and 2-benzoylpyridine hydrazones
| Autor: | Dimitra Demertzi, David Nicholls |
|---|---|
| Rok vydání: | 1983 |
| Předmět: |
chemistry.chemical_classification
Stereochemistry chemistry.chemical_element Hydrazone Zinc Nitrogen Medicinal chemistry Inorganic Chemistry Metal chemistry.chemical_compound chemistry visual_art Pyridine Materials Chemistry visual_art.visual_art_medium Physical and Theoretical Chemistry Methylene Cobalt |
| Zdroj: | Inorganica Chimica Acta. 73:37-40 |
| ISSN: | 0020-1693 |
| Popis: | Complexes derived from 2-acetylpyridine hydrazone (APH) and 2-benzoylpyridine hydrazone (BPH) have been prepared with cobalt(II) and zinc(II) salts. The mono-ligand complexes MX2L (M = Co; X = Cl, Br; M = Zn; X = Cl; L = APH, BPH; M = Co; X = NCS; L = BPH) are tetrahedral while the bis-ligand complexes (M = Co; X = Cl, Br, NCS; L = APH, BPH; M = Zn; X = Cl; L = APH, BPH) contain octahedrally coordinated metal atoms. No tris-ligand complexes have been prepared. The ligands appear to coordinate via both the pyridine and methylene nitrogen atoms. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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