Ruthenium-Catalyzed Cascade Ring-Opening Polymerization/Hydroboration for the Synthesis of Low Cross-Linking Poly (6-norbornenyldecaborane) and its Thermal Property

Autor:	Yun Liang, Jia Lin Chen, Ming Xie, Wen Lin Li, Lin Min Zhou, Qing Feng Xiong, Jun Peng Li, Han Yang
Rok vydání:	2014
Předmět:	chemistry.chemical_classification Materials science General Engineering chemistry.chemical_element Polymer Photochemistry Ring-opening polymerization Catalysis Ruthenium chemistry.chemical_compound Hydroboration chemistry Polymerization Decaborane Yield (chemistry) Polymer chemistry
Zdroj:	Advanced Materials Research. 1035:288-291
ISSN:	1662-8985
Popis:	The ruthenium catalyzed hydroboration of decaborane for the synthesis of low cross-linking poly (organodecaborane) is reported for the first time in one-pot. Based on the ruthenium-catalyzed cascade ring-opening polymerization/hydroboration reaction, the poly (6-norbornenyldecaborane) was obtained with well-defined structure, the final char yield is up to 81%. This method offers a complementary approach for the synthesis of decaborane-containing polymers.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9b10934fc2599c767bc51e79967aef4 https://doi.org/10.4028/www.scientific.net/amr.1035.288 Zobrazit plný text záznamu