Photoluminescence of solid C60 polymerized under high pressure

Autor:	Yu. A. Ossipyan, A. P. Moravsky, A. N. Izotov, R. K. Nikolaev, E. G. Ponyatovsky, E. A. Steinman, I. O. Bashkin, V. D. Negrii
Rok vydání:	1997
Předmět:	Microcrystalline Materials science Photoluminescence Polymerization Phase (matter) Analytical chemistry General Physics and Astronomy Physical and Theoretical Chemistry Radiant intensity Single crystal Intensity (heat transfer) Spectral line
Zdroj:	Chemical Physics Letters. 272:32-37
ISSN:	0009-2614
DOI:	10.1016/s0009-2614(97)00494-6
Popis:	Photoluminescence (PL) spectra were measured on the C 60 polymeric phase prepared from a single crystal and from a microcrystalline powder treated at pressures to 15 kbar and temperatures to 600 K. It was found that the high-pressure treatment resulted in a shift of the spectral intensity distribution to lower energies compared to the well-known spectrum of pristine C 60 . A set of new lines was observed. The PL spectrum of the high-pressure phase exhibited a distinct structure contrary to that of photopolymerized C 60 . The PL intensity of the high-pressure phase showed a non-monotomic temperature dependence with a slight minimumum around 150 K.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9af76407932c253d74ccee52b46c0cb https://doi.org/10.1016/s0009-2614(97)00494-6 Zobrazit plný text záznamu Full Text from ScienceDirect