Preparation of Cyclodextrin Nitrates
| Autor: | L. B. Romanova, L. S. Barinova, A. Darovskikh, Yu. M. Mikhailov, A. E. Tarasov, M. A. Rakhimova |
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| Rok vydání: | 2018 |
| Předmět: |
chemistry.chemical_classification
Reaction conditions Cyclodextrin General Chemical Engineering technology industry and agriculture 02 engineering and technology General Chemistry 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Medicinal chemistry 0104 chemical sciences carbohydrates (lipids) chemistry.chemical_compound Degree of substitution chemistry Nitrate Molar ratio Nitric acid Nitration polycyclic compounds lipids (amino acids peptides and proteins) Composition (visual arts) 0210 nano-technology |
| Zdroj: | Russian Journal of Applied Chemistry. 91:1217-1221 |
| ISSN: | 1608-3296 1070-4272 |
| DOI: | 10.1134/s1070427218070224 |
| Popis: | Nitration of α-, β-, and γ-cyclodextrins with nitric acid of various concentrations was studied. The nitration occurs similarly for all the three cyclodextrins studied. The influence of the reaction conditions on the degree of substitution of hydroxy groups in cyclodextrin by nitrate groups was examined. The composition and degree of substitution of the nitration products depend not only on the nitric acid concentration, but also on the molar ratio of HNO3 to OH groups. The results obtained allow optimization of the procedure for preparing cyclodextrin nitrates with definite topology of substitution of cyclodextrin hydroxy groups. |
| Databáze: | OpenAIRE |
| Externí odkaz: |
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