Chromium Vaporization from High-Temperature Alloys
| Autor: | Lorenz Singheiser, Egbert Wessel, K. Hilpert, M. Stanislowski, Torsten Markus |
|---|---|
| Rok vydání: | 2007 |
| Předmět: |
Materials science
Renewable Energy Sustainability and the Environment Metallurgy Oxide chemistry.chemical_element Interconnector Condensed Matter Physics Electrochemistry Cathode Chromia Surfaces Coatings and Films Electronic Optical and Magnetic Materials law.invention chemistry.chemical_compound Chromium chemistry law Vaporization Materials Chemistry Degradation (geology) |
| Zdroj: | Journal of The Electrochemical Society. 154:A295 |
| ISSN: | 0013-4651 |
| DOI: | 10.1149/1.2434690 |
| Popis: | The vaporization of chromium species from chromia scales limits the applicability of chromia-forming steels at high temperatures and is one of the major reasons for degradation in the development of planar solid oxide fuel cells (SOFCs). Cr(VI) vaporized from the interconnector is reduced at the cathode and deposits in the form of solid Cr(III)-oxide, thereby inhibiting the electrochemical processes. This work presents the first systematic study on the Cr vaporization of Cr-, Fe-, Ni-, and Co-based alloys in air and in H 2 atmospheres at high temperatures. The influence of outer oxide layers of (Cr,Mn) 3 O 4 , (Fe, Cr) 3 O 4 , Co 3 O 4 , TiO 2 , and Al 2 O 3 on the Cr vaporization is investigated. It is shown that the Cr vaporization of chromia-forming steels can be reduced by more than 90% by alloying. An estimate of the expected degradation effects on planar SOFC designs for the use of uncoated interconnector materials is used to show that in order to achieve the desired lifetimes for SOFC systems, additional Cr-retention coatings are necessary. Additionally, equilibrium vaporization measurements are carried out for pure Cr 2 O 3 (s) in humid air in order to elucidate controversies in the literature concerning the thermodynamic data of CrO 2 (OH) 2 (g). |
| Databáze: | OpenAIRE |
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