Nitrogen is a requirement for the photochemical induced 3-azabicyclo[3.3.1]nonane skeletal rearrangement!
Autor: | Paul V. Bernhardt, Craig M. Williams, Ralf Heim |
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Rok vydání: | 2005 |
Předmět: | |
Zdroj: | Tetrahedron. 61:3771-3779 |
ISSN: | 0040-4020 |
DOI: | 10.1016/j.tet.2005.02.013 |
Popis: | Specific 3-azabicyclo[3.3.1]nonane derivatives undergo skeletal cleavage when subjected to light or Lewis acidic conditions affording novel heterotricycles, which is in stark contrast to 3-oxabicyclo[3.3.1]nonanes. |
Databáze: | OpenAIRE |
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