Synthesis, structure and reactivity of μ3-SnH capped trinuclear nickel cluster

Autor: Nicole A. Torquato, Joseph M. Palasz, Quentin C. Bertrand, Felix M. Brunner, Thomas Chan, Milan Gembicky, Anthony A. Mrse, Clifford P. Kubiak
Rok vydání: 2022
Předmět:
Zdroj: Chemical Science. 13:11382-11387
ISSN: 2041-6539
2041-6520
DOI: 10.1039/d2sc04042e
Popis: The synthesis, structure, and reactivity of a μ3-SnH capped trinuclear nickel cluster, [Ni3(dppm)3(μ3-H)(μ3-SnH)], is reported. This complex undergoes oxidative addition chemistry, alkyne insertion, and subsequent hydrogenation.
Databáze: OpenAIRE