Syntheses and crystal structures of benzyltin(IV) derivatives of 2-mercaptobenzothiazole

Autor:	Chunlin Ma, Lin-Lin Qiu, Rufen Zhang, Feng Li
Rok vydání:	2010
Předmět:	Bipyramid Crystallography Chemistry Atom chemistry.chemical_element Chelation General Chemistry Crystal structure Tin 2-mercaptobenzothiazole
Zdroj:	Chinese Journal of Chemistry. 22:768-773
ISSN:	1001-604X
Popis:	The complexes (PhCH2Sn(MBT)2 (2) and (PhCH2Sn(MBT) (3) (HMBT: 2-mercaptobenzothiazole) have been synthesized and characterized by elemental analyses, and IR, 1H, 13C, 119Sn NMR spectrometries and X-ray diffraction. Studies on the crystal structures of 2 and 3 show that HMBT acts as bidentate ligand through chelation of N and S atoms. Complex 2 contains a six-coordinate tin atom with the axial angle C(15)-Sn(1)-C(22) 129.6(2)o. And the tin environment of complex 3 is a distorted cis-trigonal bipyramid with C(8)-Sn(1)-N(1) 158.80o.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d9503d4bec37dd2cc2e8587d982313a4 https://doi.org/10.1002/cjoc.20040220731 Zobrazit plný text záznamu Plný text