Acid-promoted transformations of aryl substituted diphenylphosphoryl allenes
Autor: | Albina V. Dogadina, Aleksander V. Vasilyev, Stanislav V. Lozovskiy, Alexander S. Bogachenkov |
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Rok vydání: | 2016 |
Předmět: | |
Zdroj: | Tetrahedron Letters. 57:3167-3170 |
ISSN: | 0040-4039 |
DOI: | 10.1016/j.tetlet.2016.06.026 |
Popis: | 1-(Diphenylphosphoryl)alka-1,2-dienes, bearing aryl substituents at the allene system, under the action of Bronsted (TfOH, H2SO4) or Lewis (AlCl3) acids gave rise to 3-hydroxyalk-2-en-1-yl-diphenylphosphine oxides (diphenylphosphoryl allyl alcohols) in yields of 57–98%. In some cases, the formation of (diphenylphosphoryl)indenes and phosphaheterobicyclic structures was observed. |
Databáze: | OpenAIRE |
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