Synthesis, characterization, electrochemical properties and crystal and molecular structures of [HOs3(CO)10(O2CC5H4FeC5H5)] and [{Os3H(CO)10}2(O2CC5H4FeC5H4CO2)]

Autor:	Siu Ming Lee, Kung-Kai Cheung, Wing Tak Wong
Rok vydání:	1996
Předmět:	Organic Chemistry chemistry.chemical_element Crystal structure Electrochemistry Biochemistry Redox Inorganic Chemistry Crystal Crystallography Electron transfer chemistry Materials Chemistry Cluster (physics) Osmium Physical and Theoretical Chemistry Cyclic voltammetry
Zdroj:	Journal of Organometallic Chemistry. 506:77-84
ISSN:	0022-328X
DOI:	10.1016/0022-328x(95)05657-b
Popis:	Two new air-stable triosmium clusters, [HOs 3 (CO) 10 (O 2 CC 5 H 4 FeC 5 H 5 )] ( 1 ) and [{Os 3 H(CO) 10 } 2 (O 2 CC 5 H 4 FeC 5 H 4 CO 2 )] ( 2 ), were obtained from the reaction of the labilized cluster [Os 3 (CO) 10 (CH 3 CN) 2 ] and the corresponding ferrocenecarboxylic acid and were characterized by spectroscopic methods and single-crystal X-ray diffraction studies. The redox properties of both complexes were studied by cyclic voltammetry at ambient temperature; both exhibit a reversible electron transfer process.
Databáze:	OpenAIRE
Externí odkaz:	https://explore.openaire.eu/search/publication?articleId=doi_________::d93b0d7fa60ef18e0c05f8bab1b048cd https://doi.org/10.1016/0022-328x(95)05657-b Zobrazit plný text záznamu Full Text from ScienceDirect